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学科主题: 生命有机化学
题名: A facile preparation of uronates via selective oxidation with TEMPO/KBr/Ca(OCl)(2) under aqueous conditions
其他题名: TEMPO/KBr/ Ca(ClO)2选择性氧化法方便制备糖醛酸单元
作者: Lin F(林峰) ; Peng WJ(彭文杰) ; Xu W(徐汶) ; Han XW(韩秀文) ; Yu B(俞飚)
通讯作者: 俞飚
刊名: Carbohydr. Res.
发表日期: 2004
卷: 339, 期:6, 页:1219-1223
收录类别: SCI
部门归属: 中国科学院大连化物所催化国家重点实验室; 中国科学院上海有机化学研究所生命有机国家重点实验室
英文摘要: Addition of solid Ca(OCI)(2) as the terminal oxidant in the TEMPO-mediated selective oxidation has the benefit of easier operation. A variety of partially protected saccharide derivatives (1a-1) have been successfully converted into the corresponding uronate derivatives. including disaccharide building blocks for GAG fragments and precursors to saponins. The beneficial effect of Aliquat 336 was also disclosed in the oxidation of certain substrates. (C) 2004 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000220934200028
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/18989
Appears in Collections:生命有机化学国家重点实验室_期刊论文

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Recommended Citation:
Lin F,Peng WJ,Xu W,et al. A facile preparation of uronates via selective oxidation with TEMPO/KBr/Ca(OCl)(2) under aqueous conditions[J]. Carbohydr. Res.,2004,339(6):1219-1223.
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