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学科主题: 生命有机化学
题名: Synthesis of a group of diosgenyl saponins with a combined use of glycosyl trichloroacetimidate and thioglycoside
其他题名: 使用糖基三氯乙酰亚胺酯和硫苷合成一组薯蓣皂甙
作者: Yu H(于海) ; Yu B(俞飚) ; Wu XY(吴向阳) ; Hui YZ(惠永正) ; Han XW(韩秀文)
通讯作者: 俞飚 ; 惠永正
刊名: J. Chem. Soc.-Perkin Trans. 1
发表日期: 2000-01-01
期: 9, 页:1445-1453
收录类别: SCI
部门归属: 大连化物所; 中国科学院上海有机化学研究所生命有机国家开放实验室
英文摘要: With the combined use of glycosyl trichloroacetimidates and thioglycosides, a group of natural diosgenyl saponins (1-6) are efficiently synthesized, in either a stepwise or a 'one-pot' manner. The trichloroacetimidate is empolyed as an efficient temporary hydroxy protecting group in glycosylation with the glycosyl trichloroacetimidate. The intermolecular alkyltio-group transfer is demonstrated to be a common side-reaction during glycosylation with thioglycosides.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/18905
Appears in Collections:生命有机化学国家重点实验室_期刊论文

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Recommended Citation:
Yu H,Yu B,Wu XY,et al. Synthesis of a group of diosgenyl saponins with a combined use of glycosyl trichloroacetimidate and thioglycoside[J]. J. Chem. Soc.-Perkin Trans. 1,2000(9):1445-1453.
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