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Self-supported Chiral Catalysts for Heterogeneous Asymmetric Catalysis
其他题名自负载手性催化剂在非均相不对称催化中的应用
Guo HC(郭红超); Ding KL(丁奎岭)
2011
发表期刊Chimia
ISSN0009-4293
卷号65期号:12页码:932-938
摘要A conceptually new strategy for chiral catalyst immobilization, self-supported catalysts, in heterogeneous asymmetric catalysis is highlighted in the present article. Various homochiral metal-organic polymers with diverse structures have been designed and readily prepared through coordination assembly of modular polytypic/polyfunctional ligands and metal ions without using any supports. These polymers have been successfully employed as chiral catalysts in a variety of heterogeneous asymmetric ractions, including hydrogenation, epoxidation, sulfoxidation, carbonyl-ene reactions, diethylzinc addition, and Michael addition. The self-supported heterogeneous chiral catalysts showed activity and enanioselectivity comparable or even superior to those obtained with their corresponding homogeneous counterparts, and could be readily recovered and reused several times without significant loss of activity or enantioslectivity.
学科领域金属有机化学
部门归属中国农业大学; 中科院上海有机化学研究所
URL查看原文
收录类别SCI
语种英语
WOS记录号WOS:000298835800008
引用统计
被引频次:2[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/17899
专题金属有机化学国家重点实验室
通讯作者Ding KL(丁奎岭)
推荐引用方式
GB/T 7714
Guo HC,Ding KL. Self-supported Chiral Catalysts for Heterogeneous Asymmetric Catalysis[J]. Chimia,2011,65(12):932-938.
APA 郭红超,&丁奎岭.(2011).Self-supported Chiral Catalysts for Heterogeneous Asymmetric Catalysis.Chimia,65(12),932-938.
MLA 郭红超,et al."Self-supported Chiral Catalysts for Heterogeneous Asymmetric Catalysis".Chimia 65.12(2011):932-938.
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