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学科主题: 金属有机化学
题名: An Efficient Diphosphine/Hybrid-Amine Combination for Ruthenium(II)-Catalyzed Asymmetric Hydrogenation of Aryl Ketones
其他题名: An Efficient Diphosphine/Hybrid-Amine Combination for Ruthenium(II)-Catalyzed Asymmetric Hydrogenation of Aryl Ketones
作者: Li YH(李跃辉) ; ZHOU YOUGUI ; Shi QX(石奇勋) ; Ding KL(丁奎岭) ; NOYORI RYOJI ; SANDOVAL CHRISTIAN A
通讯作者: SANDOVAL CHRISTIAN A
刊名: Adv. Synth. Catal.
发表日期: 2011
卷: 353, 期:2-3, 页:495-500
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所; Enantiotech Corp Ltd, Zhongshan Torch Hi Tech Ind Dev Zone, Zhongshan, Guangdong, Peoples R China; Nagoya Univ, Dept Chem, Nagoya, Aichi 4648601, Japan; Nagoya Univ, Res Ctr Mat Sci, Nagoya, Aichi 4648601, Japan
英文摘要: Readily available and modular hybrid amine/benzimidazole-based 1H-benzimidazole-2-methanamine (BIMA) ligands in combination with 2,3-O-isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino) butane (DIOP) afford efficient catalytic systems for the ruthenium(II)-catalyzed asymmetric hydrogenation (AH) of a number of aryl ketones. The AH proceeds smoothly with substrate-to-catalyst (S/C) molar ratios of up to 100,000 (TOF of 6500 h(-1), 8 atm) giving chiral alcohols in up to 99% ee.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000287669600036
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/17887
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Li YH,ZHOU YOUGUI,Shi QX,et al. An Efficient Diphosphine/Hybrid-Amine Combination for Ruthenium(II)-Catalyzed Asymmetric Hydrogenation of Aryl Ketones[J]. Adv. Synth. Catal.,2011,353(2-3):495-500.
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