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学科主题: 金属有机化学
题名: Charge-Transfer Effect on Chiral Phosphoric Acid Catalyzed Asymmetric Baeyer-Villiger Oxidation of 3-Substituted Cyclobutanones Using 30% Aqueous H2O2 as the Oxidant
其他题名: 手性磷酸催化的不对称BV氧化反应中的电荷转移效应
作者: Xu SM(徐森苗) ; Wang Z(王正) ; Zhang XM(张绪穆) ; Ding KL(丁奎岭)
通讯作者: 丁奎岭
刊名: Chin. J. Chem.
发表日期: 2010-01-01
卷: 28, 期:9, 页:1731-1735
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所; Rutgers State Univ
英文摘要: The intermolecular charge-transfer effect has been employed for the first time as a modulating approach to affect the enantioselectivity in asymmetric catalysis by taking the chiral phosphoric acid catalyzed asymmetric Baeyer-Villiger oxidation of 3-aryl cyclobutanones as the reaction prototype. It was found that the electron acceptor additives were able to effectively tune the enantioselectivity via donor-acceptor interaction with the catalyst and up to 9% enhancement of ee value was observed in a favorable case.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000282998700035
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/17867
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Xu SM,Wang Z,Zhang XM,et al. Charge-Transfer Effect on Chiral Phosphoric Acid Catalyzed Asymmetric Baeyer-Villiger Oxidation of 3-Substituted Cyclobutanones Using 30% Aqueous H2O2 as the Oxidant[J]. Chin. J. Chem.,2010,28(9):1731-1735.
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