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学科主题: 金属有机化学
题名: Spiro Skeletons: A Class of Privileged Structure for Chiral Ligand Design
其他题名: 螺环骨架: 手性配体设计中的一类优势结构
作者: Ding KL(丁奎岭) ; Han ZB(韩召斌) ; Wang Z(王正)
通讯作者: 丁奎岭
刊名: Chem.-Asian J.
发表日期: 2009
卷: 4, 期:1, 页:32-41
收录类别: SCI
部门归属: 上海有机所
英文摘要: This Focus Review highlights the exciting results obtained in the area of asymmetric catalysis using spirobiindane- or spirobifluorene-based chiral ligands. The spiro, mono, and bidentate ligands have been successfully applied in a wide range of transition-metal-catalyzed asymmetric reactions, including hydrogenations, carbon-carbon and carbon-heteroatom coupling reactions, with superior or comparable enantioselectivities to those obtained by using the related ligands bearing other backbones, thus proving that the spiro skeleton is a type of privileged structure for chiral ligand design. It is expected that the spiro concept for chiral ligand design will stimulate the future efforts to understand the features that account for their broad applicability and to apply this understanding to seek new privileged chiral ligands and catalysts.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000262582400003
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/17865
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Ding KL,Han ZB,Wang Z. Spiro Skeletons: A Class of Privileged Structure for Chiral Ligand Design[J]. Chem.-Asian J.,2009,4(1):32-41.
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