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学科主题: 金属有机化学
题名: Hybrid NH2-Benzimidazole Ligands for Efficient Ru-Catalyzed Asymmetric Hydrogenation of Aryl Ketones
其他题名: Hybrid NH2-Benzimidazole Ligands for Efficient Ru-Catalyzed Asymmetric Hydrogenation of Aryl Ketones
作者: Li YH(李跃辉) ; Ding KL(丁奎岭) ; SANDOVAL CHRISTIAN A
通讯作者: SANDOVAL CHRISTIAN A
刊名: Org. Lett.
发表日期: 2009
卷: 11, 期:4, 页:907-910
收录类别: SCI
部门归属: 上海有机所
英文摘要: Readily available hybrid NH2/benzimidazole ligands (R-bimaH, 1) dramatically influence the outcome of established Ru-based catalysts during asymmetric hydrogenation of aryl ketones. The benzimidazole functionality results in reversal of the typically observed chiral induction and allows for hydrogenation to be uncharacteristically conducted in nonprotic solvents. The developed systems efficiently catalyzed the AH of a number of ketones in up to 99% ee.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000263299000031
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/17863
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Li YH,Ding KL,SANDOVAL CHRISTIAN A. Hybrid NH2-Benzimidazole Ligands for Efficient Ru-Catalyzed Asymmetric Hydrogenation of Aryl Ketones[J]. Org. Lett.,2009,11(4):907-910.
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