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学科主题: 金属有机化学
题名: Ferrocene-based bidentate phosphonite ligands for rhodium(I)-catalyzed enantioselective hydroformylation
其他题名: Ferrocene-based bidentate phosphonite ligands for rhodium(I)-catalyzed enantioselective hydroformylation
作者: Peng XG(彭新高) ; Wang Z(王正) ; Xia CG(夏春谷) ; Ding KL(丁奎岭)
通讯作者: 丁奎岭
刊名: Tetrahedron Lett.
发表日期: 2008
卷: 49, 期:33, 页:4862-4864
收录类别: SCI
部门归属: 上海有机所; 兰州化物所
英文摘要: A new class of chiral modular bidentate phosphonite ligands has been synthesized in good overall yields by using cheap trans-1,2-diaminocyclohexane and ferrocene as starting materials, and applied in the Rh(I)-catalyzed asymmetric hydroformylation of vinyl acetate and styrene to afford the Corresponding optically active aldehydes with good regioselectivity (up to 16.9 b/l ratio) and moderate to good enantioselectivity (up to 83% ee). The substituents on the backbone of the ligands are found to exhibit a remarkable effect on both the regio- and enantioselectivity of the catalysis. (C) 2008 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000258274200013
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/17845
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Peng XG,Wang Z,Xia CG,et al. Ferrocene-based bidentate phosphonite ligands for rhodium(I)-catalyzed enantioselective hydroformylation[J]. Tetrahedron Lett.,2008,49(33):4862-4864.
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