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Self-supported chiral catalysts for heterogeneous enantioselective reactions
其他题名非均相对映选择性反应中的手性自负载催化剂
Ding KL(丁奎岭); Wang Z(王正); Shi L(石磊)
2007
发表期刊Pure Appl. Chem.
ISSN0033-4545
卷号79期号:9页码:1531-1540
摘要The development of a new strategy to immobilize the homogeneous chiral catalysts for enantioselective reactions is highly desirable in order to overcome some drawbacks of conventional approaches. In this lecture, a conceptually new strategy for heterogenization of homogeneous chiral catalysts (i.e., "self-supporting" approach) is presented. The concept focuses on the use of homochiral metal-organic coordination polymers generated by self-assembly of chiral multitopic ligands with metal ions as the heterogeneous catalysts, and thus obviating the need of any exogenous support. The application of this "self-supporting" strategy has been exemplified in heterogeneous catalysis of asymmetric carbonyl-ene, sulfoxidation, and epoxidation, as well as asymmetric hydrogenation reactions.
学科领域金属有机化学
部门归属中科院上海有机化学研究所金属有机化学国家重点实验室
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收录类别SCI
语种英语
WOS记录号WOS:000239105500003
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被引频次:96[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/17833
专题金属有机化学国家重点实验室
通讯作者Ding KL(丁奎岭)
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Ding KL,Wang Z,Shi L. Self-supported chiral catalysts for heterogeneous enantioselective reactions[J]. Pure Appl. Chem.,2007,79(9):1531-1540.
APA 丁奎岭,王正,&石磊.(2007).Self-supported chiral catalysts for heterogeneous enantioselective reactions.Pure Appl. Chem.,79(9),1531-1540.
MLA 丁奎岭,et al."Self-supported chiral catalysts for heterogeneous enantioselective reactions".Pure Appl. Chem. 79.9(2007):1531-1540.
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