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学科主题: 金属有机化学
题名: Self-supported chiral catalysts for heterogeneous enantioselective reactions
其他题名: 非均相对映选择性反应中的手性自负载催化剂
作者: Ding KL(丁奎岭) ; Wang Z(王正) ; Shi L(石磊)
通讯作者: 丁奎岭
刊名: Pure Appl. Chem.
发表日期: 2007
卷: 79, 期:9, 页:1531-1540
收录类别: SCI
部门归属: 中科院上海有机化学研究所金属有机化学国家重点实验室
英文摘要: The development of a new strategy to immobilize the homogeneous chiral catalysts for enantioselective reactions is highly desirable in order to overcome some drawbacks of conventional approaches. In this lecture, a conceptually new strategy for heterogenization of homogeneous chiral catalysts (i.e., "self-supporting" approach) is presented. The concept focuses on the use of homochiral metal-organic coordination polymers generated by self-assembly of chiral multitopic ligands with metal ions as the heterogeneous catalysts, and thus obviating the need of any exogenous support. The application of this "self-supporting" strategy has been exemplified in heterogeneous catalysis of asymmetric carbonyl-ene, sulfoxidation, and epoxidation, as well as asymmetric hydrogenation reactions.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000239105500003
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/17833
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Ding KL,Wang Z,Shi L. Self-supported chiral catalysts for heterogeneous enantioselective reactions[J]. Pure Appl. Chem.,2007,79(9):1531-1540.
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