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学科主题: 金属有机化学
题名: Self-supported chiral catalysts for heterogeneous enantioselective reactions hydrogenation; oxidation; self-assembly
其他题名: 非均相对映选择性反应中的自负载手性催化剂
作者: Ding KL(丁奎岭) ; Wang Z(王正) ; Wang XW(王兴旺) ; Liang YX(梁毓学) ; Wang XS(王喜胜)
通讯作者: 丁奎岭
刊名: Chem.-Eur. J.
发表日期: 2006-01-01
卷: 12, 期:20, 页:5188-5197
收录类别: SCI
部门归属: 中科院上海有机化学研究所金属有机化学国家重点实验室
英文摘要: The development of heterogeneous chiral catalysts for enantioselective reactions is highly desirable in order to overcome some drawbacks of homogeneous catalysts. Different from the conventional approaches by using various types of supports or biphasic systems for the recovery and reuse of homogeneous catalysts, a conceptually new strategy for heterogenization of homogeneous chiral catalysts, that is. a "self-supporting" approach, has been developed to use homochiral metal-organic coordination polymers generated by the self-assembly of chiral inultitopic ligands with metal ions, and thus obviates the use of any support. In this concept article, the success of this "self-supporting" strategy will be exemplified in heterogeneous catalysis of asymmetric carbonyl-ene, sulfoxidation, epoxidation, and asymmetric hydrogenation reactions.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/17815
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Ding KL,Wang Z,Wang XW,et al. Self-supported chiral catalysts for heterogeneous enantioselective reactions hydrogenation; oxidation; self-assembly[J]. Chem.-Eur. J.,2006,12(20):5188-5197.
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