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学科主题: 金属有机化学
题名: Bulky achiral triarylphosphines mimic BINAP in Ru(II)-catalyzed asymmetric hydrogenation of ketones phosphines; ruthenium
其他题名: 体积庞大的三芳基膦在Ru(II)催化的酮的不对称氢化反应中可以模拟BINAP
作者: Jing Q(荆庆) ; Zhang X(张雪) ; Sun J(孙杰) ; Ding KL(丁奎岭)
通讯作者: 丁奎岭
刊名: Adv. Synth. Catal.
发表日期: 2005-01-01
卷: 347, 期:9, 页:1193-1197
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: In the present work, we report on catalysis of the enantioselective hydrogenation of ketones with Ru(II) complexes composed of cheap achiral monodentate phosphine ligands in combination with an enantiopure 1,2-diamine, affording a variety of optically active secondary alcohols with high efficiency and enantioselectivity. The steric impact of achiral monophosphine ligands in Ru complexes was found to be a critical factor for the high enantioselectivity of the reaction. This finding throws some light on a long-standing challenge, the high cost of chiral bisphosphine ligands, associated with an industrial application of the asymmetric hydrogenation of ketones.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/17795
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Jing Q,Zhang X,Sun J,et al. Bulky achiral triarylphosphines mimic BINAP in Ru(II)-catalyzed asymmetric hydrogenation of ketones phosphines; ruthenium[J]. Adv. Synth. Catal.,2005,347(9):1193-1197.
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