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学科主题: 金属有机化学
题名: Assembled enantioselective catalysts for carbonyl-ene reactions
其他题名: 用于羰基-ENE反应的组装体手性催化剂
作者: Guo HC(郭红超) ; Wang XW(王兴旺) ; Ding KL(丁奎岭)
通讯作者: 丁奎岭
刊名: Tetrahedron Lett.
发表日期: 2004
卷: 45, 期:9, 页:2009-2012
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所
英文摘要: A new strategy for generating assembled polymeric chiral titanium complexes using linked bis-BINOL ligands have been developed, and the assembled catalysts showed excellent enantioselectivity (up to 96.5% ee) for carbonyl-ene reaction under heterogeneous conditions to afford corresponding alpha-hydroxy esters in high yield. The linkers between two BINOL units of the ligands in the assembled catalysts were found to have significant impact on the enantioselectivity of reaction, which demonstrated the importance of the supramolecular structures of the assemblies for their catalytic behaviours. (C) 2004 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000189116200045
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/17773
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Guo HC,Wang XW,Ding KL. Assembled enantioselective catalysts for carbonyl-ene reactions[J]. Tetrahedron Lett.,2004,45(9):2009-2012.
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