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Supramolecular assemblies of (+/-)-2,2 '-dihydroxy-1,1 '-binaphthyl with 2,2 '-bipyridine and naphthodiazine
其他题名外消旋BINOL与2,2‘-联吡啶和吩嗪的超分子组装体结构研究
Ji BM(吉保明); Chen HT(陈花婷); Du CX(杜晨霞); Ding KL(丁奎岭)
2004
发表期刊Chin. J. Chem.
ISSN1001-604X
卷号22期号:9页码:1045-1051
摘要Supramolecular assemblies of (+/-)-2,2'-dihydroxy-1,1'-binaphthyl (BINOL, A), with aza donor molecules including 2,2'-bipyridine (B) and naphthodiazine (C), have been synthesized and characterized by single-crystal X-ray diffraction methods. Two inclusion complexes crystallize in the triclinic system with P-1 space group. In the inclusion complex between A and B, two molecules of A and two molecules of B are linked each other by intermolecular hydrogen bonds with two molecules of water as the bridges, forming a centrosymmetric dimer with formula of A(2)(H2O)(2)B-2; while in the inclusion complex between A and C, the molecule C virtually acts as a bridge to link molecules A through intermolecular O-H...N hydrogen bonds, forming a short-chain supramolecular block with a formula of A(2).C-3. Besides the hydrogen bonding interaction between the host and guest molecules, pi-pi stacking interactions also play an important role in the solid-state packing of these two inclusion complexes. The structural information disclosed on the complex between dihydroxy compound and aza hydrogen bond acceptors in this work would be particularly important for the rational design of supramolecular organic functional materials.
学科领域有机化学
部门归属洛阳师范学院化学系; 郑州大学化学系; 中国科学院上海有机化学研究所
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收录类别SCI
语种英语
WOS记录号WOS:000223842000033
引用统计
被引频次:5[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/17767
专题金属有机化学国家重点实验室
通讯作者Ji BM(吉保明); Ding KL(丁奎岭)
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GB/T 7714
Ji BM,Chen HT,Du CX,et al. Supramolecular assemblies of (+/-)-2,2 '-dihydroxy-1,1 '-binaphthyl with 2,2 '-bipyridine and naphthodiazine[J]. Chin. J. Chem.,2004,22(9):1045-1051.
APA 吉保明,陈花婷,杜晨霞,&丁奎岭.(2004).Supramolecular assemblies of (+/-)-2,2 '-dihydroxy-1,1 '-binaphthyl with 2,2 '-bipyridine and naphthodiazine.Chin. J. Chem.,22(9),1045-1051.
MLA 吉保明,et al."Supramolecular assemblies of (+/-)-2,2 '-dihydroxy-1,1 '-binaphthyl with 2,2 '-bipyridine and naphthodiazine".Chin. J. Chem. 22.9(2004):1045-1051.
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