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学科主题: 有机化学
题名: Supramolecular assemblies of (+/-)-2,2 '-dihydroxy-1,1 '-binaphthyl with 2,2 '-bipyridine and naphthodiazine
其他题名: 外消旋BINOL与2,2‘-联吡啶和吩嗪的超分子组装体结构研究
作者: Ji BM(吉保明) ; Chen HT(陈花婷) ; Du CX(杜晨霞) ; Ding KL(丁奎岭)
通讯作者: 吉保明 ; 丁奎岭
刊名: Chin. J. Chem.
发表日期: 2004
卷: 22, 期:9, 页:1045-1051
收录类别: SCI
部门归属: 洛阳师范学院化学系; 郑州大学化学系; 中国科学院上海有机化学研究所
英文摘要: Supramolecular assemblies of (+/-)-2,2'-dihydroxy-1,1'-binaphthyl (BINOL, A), with aza donor molecules including 2,2'-bipyridine (B) and naphthodiazine (C), have been synthesized and characterized by single-crystal X-ray diffraction methods. Two inclusion complexes crystallize in the triclinic system with P-1 space group. In the inclusion complex between A and B, two molecules of A and two molecules of B are linked each other by intermolecular hydrogen bonds with two molecules of water as the bridges, forming a centrosymmetric dimer with formula of A(2)(H2O)(2)B-2; while in the inclusion complex between A and C, the molecule C virtually acts as a bridge to link molecules A through intermolecular O-H...N hydrogen bonds, forming a short-chain supramolecular block with a formula of A(2).C-3. Besides the hydrogen bonding interaction between the host and guest molecules, pi-pi stacking interactions also play an important role in the solid-state packing of these two inclusion complexes. The structural information disclosed on the complex between dihydroxy compound and aza hydrogen bond acceptors in this work would be particularly important for the rational design of supramolecular organic functional materials.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000223842000033
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/17767
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Ji BM,Chen HT,Du CX,et al. Supramolecular assemblies of (+/-)-2,2 '-dihydroxy-1,1 '-binaphthyl with 2,2 '-bipyridine and naphthodiazine[J]. Chin. J. Chem.,2004,22(9):1045-1051.
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