中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 金属有机化学国家重点实验室  > 期刊论文
学科主题: 金属有机化学
题名: A new type of C^2-symmetric bisphospine ligands with a cyclobutane backbone: Preactical synthesis and application
其他题名: 一类新的具有C^2-对称性和四元环骨架的双膦配体:合成与应用
作者: Zhao DB(赵东波) ; Ding KL(丁奎岭)
通讯作者: 丁奎岭
刊名: Org. Lett.
发表日期: 2003-01-01
卷: 5, 期:8, 页:1349-1351
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: A highly efficient and practical optical resolution of anti-head-to-head reacemic coumarin dimer, (±)-5, by molecular complexation with TADDOL(6) through gydrogen bonding and a convenient transformation of enantiopure 5 to a new type of C^3-symmetric bisphosphine ligand (3) have been achieved. The asymmetric induction efficiency of these chiral bisphosphine ligands was evaluated in Pd-catalyzed asymmetric allylic substitution, affording the allylic substitution products in excellent yield (up to 99%) and enantioselectivity (up to 98.9% ee)
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/17761
Appears in Collections:金属有机化学国家重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2003121.pdf(78KB)----开放获取--View Download

Recommended Citation:
Zhao DB,Ding KL. A new type of C^2-symmetric bisphospine ligands with a cyclobutane backbone: Preactical synthesis and application[J]. Org. Lett.,2003,5(8):1349-1351.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[赵东波]'s Articles
[丁奎岭]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[赵东波]‘s Articles
[丁奎岭]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2003121.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace