中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 金属有机化学国家重点实验室  > 期刊论文
学科主题: 有机化学
题名: Molecular assembly in an inclusion crystalof tris(2-benzimidazylmethyl)amine with 4-nitrobenzoic acid of tris(2-benzimidazylmethyl)amine with 4-nitrobenzoic acid
其他题名: 三(2-苯并咪唑甲基)胺与4-硝基苯甲酸的分子晶体种的分子组装
作者: Ji BM(吉保明) ; Du CX(杜晨霞) ; Zhu Y(朱玉) ; Ding KL(丁奎岭)
通讯作者: 丁奎岭
刊名: J. Chem. Crystallogr.
发表日期: 2000-01-01T00:00:00Z
卷: 30, 期:12, 页:783-788
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室; 郑州大学; 洛阳师范学院
英文摘要: A 1:2 inclusion compound of tris(2-benzimidazylmethyl)amine with 4-nitrobenzoic acid [(C^24H^21N^7).(C^7H&5NO^2)^2] has been prepared and the molecular assembly in solid state has been determined by X-ray crystal structural analysis. The crystal structure (C2/c,a=25.488(5),b=13.304(3),c=21.479(4) A β=93.35(3)°,Z=8,R=0.065) consists of discrete dimeric inclusion compounds joined together by N(5)...N(6) intermolecular hydrogen bonds between pairs of centrosymmetrically related benzimidazole rings of the hosts. There are two types of guest molecules in the crystal, one is incorporated within the cavity of the host via three in tramolecular N-H...O hydrogen bonds while the other is situated outside the cavity and connected with he host through one O-H...N hydrogen bond. The π-π stacking interactions between guests and benzimidazole rings result in one -dimensional columns. The aromatic face-face interactions between neighbouring columns facilitate the assembly of those columns into two-dimensional layers.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/17747
Appears in Collections:金属有机化学国家重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2002104.pdf(286KB)----开放获取--View Download

Recommended Citation:
Ji BM,Du CX,Zhu Y,et al. Molecular assembly in an inclusion crystalof tris(2-benzimidazylmethyl)amine with 4-nitrobenzoic acid of tris(2-benzimidazylmethyl)amine with 4-nitrobenzoic acid[J]. J. Chem. Crystallogr.,2000,30(12):783-788.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[吉保明]'s Articles
[杜晨霞]'s Articles
[朱玉]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[吉保明]‘s Articles
[杜晨霞]‘s Articles
[朱玉]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2002104.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace