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学科主题: 金属有机化学
题名: Synthesis of aminophosphine ligands with binaphthyl backbones for silver(I)-catalyzed enantioselective allylation of benzaldehyde
其他题名: 含有联萘骨架的氨基膦配体的合成及其在 Ag(1) 催化的不对称烯丙基化反应中的应用
作者: Wang Y(王以) ; Ji BM(吉保明) ; Ding KL(丁奎岭)
通讯作者: 丁奎岭
刊名: Chin. J. Chem.
发表日期: 2002-01-01
卷: 20, 期:11, 页:1300-1312
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: A series of aminophosphine ligands was synthesized from 2-amino-2'-hydroxy-1,1'-binaphthyl NOBIN). Their asymmetric induction efficiency was examined for silver(I) catalyzed enantioselective allylation reaction of benzaldehyde with allyltributyltin. Under the optimized reaction conditions, quantitative yield as well as moderate ee value (54% ee) of product was achieved by the catalysis with silver(I)/3 complex. The effects of the binaphthyl backbone and the substituteds situated at chelating N,P atoms on enantioselectivity of the reaction were also discussed.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/17745
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Wang Y,Ji BM,Ding KL. Synthesis of aminophosphine ligands with binaphthyl backbones for silver(I)-catalyzed enantioselective allylation of benzaldehyde[J]. Chin. J. Chem.,2002,20(11):1300-1312.
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