中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 金属有机化学国家重点实验室  > 期刊论文
学科主题: 有机化学
题名: A new method for optical resolution of BINOL by molecular complexation with (S)-5-oxopyrrolidine-2-carboxanilide
其他题名: 用(S)-5-oxopyrrolidine-2-carboxanilide 作为拆分试剂通过分子络合进行的BINOL光学拆分新方法
作者: Du HF(杜海峰) ; Ji BM(吉保明) ; Wang Y(王洋) ; Sun J(孙杰) ; Meng JB(孟继本) ; Ding KL(丁奎岭)
通讯作者: 丁奎岭
刊名: Tetrahedron Lett.
发表日期: 2002
卷: 43, 期:30, 页:5273-5276
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室; 复旦大学; 南开大学
英文摘要: A new method for optical resolution of racemic 1,1'-bi-2-naphthol(BINOL) has been developed through molecular complexation with a cheap and readily accessible (S)-5-oxopyrrolidine-2-carboxanilide, affording the enantioenriched BINOL in up to 70.4% ee and 74% yield. X-ray structural analysis of a molecular crystal formed between (R)-BINOL and (S)-5-oxopyrrolidine-2-carboxanilide indicates that the hydrogen bonding interactions between the carbonyl groups of amides and the hydroxyl groups of (R)-BINOL predominate in the molecular complex formaion. The chiral features of the amide and the complementary molecular packing in the crystal lattice control the stereochemistry of the guest in the molecular crystal.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000176727200015
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/17743
Appears in Collections:金属有机化学国家重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2002102.pdf(89KB)----开放获取--View Download

Recommended Citation:
Du HF,Ji BM,Wang Y,et al. A new method for optical resolution of BINOL by molecular complexation with (S)-5-oxopyrrolidine-2-carboxanilide[J]. Tetrahedron Lett.,2002,43(30):5273-5276.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[杜海峰]'s Articles
[吉保明]'s Articles
[王洋]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[杜海峰]‘s Articles
[吉保明]‘s Articles
[王洋]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2002102.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace