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学科主题: 金属有机化学
题名: Synthesis of a new type of chiral amino phosphine ligands for asymmetric catalysis
其他题名: 一类新型氨基膦配体的合成及其在不对称催化中的应用
作者: Wang Y(王以) ; Li X(李欣) ; Ding KL(丁奎岭)
通讯作者: 丁奎岭
刊名: Tetrahedron-Asymmetry
发表日期: 2002
卷: 13, 期:12, 页:1291-1297
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: This article describes the synthesis of a new type of chiral amino phosphine ligands from an amino naphthol starting material derived by asymmetric 1-aminoalkylation of 2-naphthol with (R)-1-phenylethylamine and benzaldehyde. The asymmetric induction properties of the ligands in the Pd(0)-catalyzed allylic substiution of 1,3-diphenylprop-2-en-1-yl acetate with dimethyl malonate has also been investigated, with near-quantitative yields and ee of up to 72.2% of the product being obtained under the optimized reaction conditions.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000177467600009
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/17741
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Wang Y,Li X,Ding KL. Synthesis of a new type of chiral amino phosphine ligands for asymmetric catalysis[J]. Tetrahedron-Asymmetry,2002,13(12):1291-1297.
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