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学科主题: 金属有机化学
题名: The synthesis of a new generation of MAP ligands containing two types of chiral elements for asymmetic catalysis
其他题名: 新一代MAP配位的合成及在不对称催化中的应用
作者: Wang Y(王以) ; Li X(李欣) ; Ding KL(丁奎岭)
通讯作者: 丁奎岭
刊名: Tetrahedron Lett.
发表日期: 2002-01-01
卷: 43, 期:1, 页:159-161
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: A series of novel aminophosphine ligands containing both axial and central chirality have been synthesized for the first time from NOBIN and tartaric acid derivatives. Their capability for asymmetric induction in the Pd-catalyzed reaction of 1,3-diphenylprop-2-en-1-yl acetate and dimethyl malonate was investigated and the results celarly demonostrated that correct assembly of axial chirality in the scaffold and central chirality of the modification group was very important for achieving higher enantioselectivity in the reaction. In a matched case, the asymmetric allylation product could be obtained in 85.6% ee.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/17739
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Wang Y,Li X,Ding KL. The synthesis of a new generation of MAP ligands containing two types of chiral elements for asymmetic catalysis[J]. Tetrahedron Lett.,2002,43(1):159-161.
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