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学科主题: 金属有机化学
题名: Asymmetric activation of chiral alkoxyzinc catalysts by chiral nitrogen activators for dialkylzinc addition to aldehydes: Super High-Throughput screening of combinatorial libraries of chiral ligands and activators by by HPLC-CD/UV and HPLC-OR/RIU systems
其他题名: 用手性含氮活化剂对手性烷基氧锌络合物进行不对称活化: 用 HPLC-CD/UV 和HPLEC-OR/RIU系统高通量筛选手性配体和活化剂库
作者: Koichi Mikami ; Remy angelaud ; Ding KL(丁奎岭) ; Akihiro Ishii ; Akito Tanaka ; Naotaka Sawada ; Kenichi Kudo ; Masaaki Senda
通讯作者: Koichi Mikami
刊名: Chem.-Eur. J.
发表日期: 2001-01-01
卷: 7, 期:3, 页:730-737
收录类别: SCI
部门归属: 日本东京工业大学;中国科学院上海有机化学研究所金属有机化学开放实验室; 第一日本樱机日本JASCO公司
英文摘要: Asymmetric catalysts, prepared by chiral ligand exchange or chiral modification, can evolve further into highly activated catalysts through engineering with chiral activators. Two new methodologies for "super high-throughput screening" (SHTS) of chiral ligands and activators have been developed as a combination of HPLC-CD/UV (CD/UV=circular dichrosim/ultraviolet spectroscopy) or -OR/RIU (OR?RIU=optical rotation/refractive index unit) with a combinatorial chemistry (CC)
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/17729
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Koichi Mikami,Remy angelaud,Ding KL,et al. Asymmetric activation of chiral alkoxyzinc catalysts by chiral nitrogen activators for dialkylzinc addition to aldehydes: Super High-Throughput screening of combinatorial libraries of chiral ligands and activators by by HPLC-CD/UV and HPLC-OR/RIU systems[J]. Chem.-Eur. J.,2001,7(3):730-737.
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