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Synthesis of some novel amino phenols with ocatahydro-1,1'-bi-nahthyl backbone
Alternative Title一些含有氢-1,1'-联萘骨架的新型氨基酚配体的合成
Guo H(郭辉); Wang Y(王以); Ding KL(丁奎岭)
2001
Source PublicationChin. J. Chem.
ISSN1001-604X
Volume19Issue:1Pages:52-57
AbstractA seriesof new octahydro-1,1'-binaphthyl derivatives, namely (R)-(+)-2-(N,N-dialkylamino)-2'hydroxy-5,5',6,6'7,7'8,8'-octahydro-1,1'-binaphthyls(7,9), have been synthesized. Their asymmetric induction for enantioselective addition of Et^2Zn to benzaldehyde was examined and it was found that (R)-(+)-2-(N-cyclohexyl-N-methylamino)-2'-hydroxy-5,5'6,6'7,7'8,8'-octahydro-1,'-binaphehyl(9c) exhibited the best asymmetric induction among the ligands prepared, up to 55% ee of 1-phenylpropanol being obtained.
Subject Area有机化学
Department中国科学院上海有机化学研究所金属有机化学开放实验室
URL查看原文
Indexed BySCI
Language英语
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/17725
Collection金属有机化学国家重点实验室
Corresponding AuthorDing KL(丁奎岭)
Recommended Citation
GB/T 7714
Guo H,Wang Y,Ding KL. Synthesis of some novel amino phenols with ocatahydro-1,1'-bi-nahthyl backbone[J]. Chin. J. Chem.,2001,19(1):52-57.
APA 郭辉,王以,&丁奎岭.(2001).Synthesis of some novel amino phenols with ocatahydro-1,1'-bi-nahthyl backbone.Chin. J. Chem.,19(1),52-57.
MLA 郭辉,et al."Synthesis of some novel amino phenols with ocatahydro-1,1'-bi-nahthyl backbone".Chin. J. Chem. 19.1(2001):52-57.
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