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学科主题: 有机化学
题名: Synthesis and crystallographic characterization of a palladium (II) complex with the ligand (4-ethoxyphenyl)[2-amino-5-methyl)phenyl]telluride
其他题名: (4-乙氧苯基)[(2-氨基-5-甲基)苄基]碲配体的合成和晶体学表征
作者: Ji BM(吉保明) ; Ding KL(丁奎岭)
通讯作者: 丁奎岭
刊名: Inorg. Chem. Commun.
发表日期: 1999-01-01
页: 347-350
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所
英文摘要: The complex LPdCl^2 (L=4-ethoxyphenyl)[(2-amino-5-methyl)phenyl]telluride) was preared by reaction of the ligand with Li^2 PdCl^4 in methanol solution. Red prismatic crystals (LPdCl^2.DMSO.H^2O) suitable for X-ray analysis were obtained by slow evaporation from DMSO-H^2O mixed solvent. This is the first well-characterized palladium (II) complex containing a bidentate (N and Te) ligand (space group P1:a=12.068(2), b=12.651(2), c=8.186(2) A; α=99.74(2), β=94.22(2), γ=63.07(1)~o; R=0.0035, Rw=0.062). Twounidentate chloride ions are coplanar with the Pd, N and Te atoms of the ligand. The metal environment is a distorted panar geoe\metry. The two Pd-Cl bonds are inequivalent; one Pd-Cl(Pd-Cl(2), 2.371 A) distance is much longer than the other (Pd-Cl(1), 2.301 A).
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/17715
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Ji BM,Ding KL. Synthesis and crystallographic characterization of a palladium (II) complex with the ligand (4-ethoxyphenyl)[2-amino-5-methyl)phenyl]telluride[J]. Inorg. Chem. Commun.,1999:347-350.
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