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学科主题: 氟化学 ; 生命有机化学
题名: Synthesis of 2 ',3 '-dideoxy-6 '-fluorocarbocyclic nucleosides via Reformatskii-Claisen rearrangement
其他题名: 由Reformatskii-Claisen重排反应合成2,3-双脱氧-6-氟碳环核苷
作者: Yang Y(杨义) ; Zheng F(郑峰) ; Qing FL(卿凤翎)
通讯作者: 卿凤翎
刊名: Tetrahedron
发表日期: 2011
卷: 67, 期:19, 页:3388-3394
收录类别: SCI
部门归属: 中科院上海有机化学研究所; 东华大学
英文摘要: 2',3'-Dideoxy-6'-fluorocarbocyclic nucleosides, analogues of highly bioactive carbovir and abacavir were synthesized. The notable steps were the incorporation of fluoromethylene group by way of silicon-induced Reformatskii-Claisen rearrangement of allyl bromofluoroacetate, the construction of the carbocyclic ring via ring-closing metathesis (RCM) and the introduction of base by Mitsunobu reaction. (C) 2011 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000290602000013
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/17699
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Yang Y,Zheng F,Qing FL. Synthesis of 2 ',3 '-dideoxy-6 '-fluorocarbocyclic nucleosides via Reformatskii-Claisen rearrangement[J]. Tetrahedron,2011,67(19):3388-3394.
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