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学科主题: 氟化学
题名: Novel water and oil repellent POSS-based organic/inorganic nanomaterial: Preparation, characterization and application to cotton fabrics
其他题名: Novel water and oil repellent POSS-based organic/inorganic nanomaterial: Preparation, characterization and application to cotton fabrics
作者: Gao Y(高宇) ; He CL(何创龙) ; Huang YG(黄焰根) ; Qing FL(卿凤翎)
通讯作者: 卿凤翎
刊名: Polymer
发表日期: 2010
卷: 51, 期:25, 页:5997-6004
收录类别: SCI
部门归属: 东华大学; 中国科学院上海有机化学研究所
英文摘要: A series of polyhedral oligomeric silsesquioxane (POSS) based hybrid terpolymers P(POSS-MMA-(HFPO)(3)MA) were synthesized and characterized by NMR, FT-IR, GPC, DSC and TG. The thermal properties of these terpolymers were improved by the introduction of POSS cage. The cotton fabrics coated with these terpolymers possessed excellent water and oil repellency. The water and salad oil contact angle could be achieved from similar to 140 degrees to 152 degrees and from similar to 127 degrees to 144 degrees respectively as the content of POSS in the terpolymer increased from 6.4 wt% to 13.4 wt%. Compared with P(MMA-(HFPO)(3)MA) copolymer-coated cotton fabrics, POSS-based terpolymer coated cotton fabrics showed better oil repellency with a tendency of first increasing and then decreasing with an increase of the POSS content. The n-hexadecane (surface tension: 27.4 mN/m, 20 degrees C) contact angle reached similar to 117 degrees for coated cotton fabrics with terpolymer containing 9.5 wt% of POSS. (C) 2010 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000284793500015
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/17695
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Gao Y,He CL,Huang YG,et al. Novel water and oil repellent POSS-based organic/inorganic nanomaterial: Preparation, characterization and application to cotton fabrics[J]. Polymer,2010,51(25):5997-6004.
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