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学科主题: 氟化学 ; 生命有机化学
题名: Stereoselective Reformatskii-Claisen rearrangement: synthesis of 2 ',3 '-dideoxy-6 ',6 '-difluoro-2 '-thionucleosides
其他题名: 立体选择性的Reformatskii-Claisen重排:2,3-二去氧-6,6-二氟-2-硫杂核苷的合成
作者: Zheng F(郑峰) ; Zhang XG(张新刚) ; Qing FL(卿凤翎)
通讯作者: 卿凤翎
刊名: Chem. Commun.
发表日期: 2009
期: 12, 页:1505-1507
收录类别: SCI
部门归属: 上海有机所
英文摘要: A new approach for the stereoselective synthesis of 2 ',3 '-dideoxy-6 ',6 '-difluoro-2 '-thionucleosides, analogues of highly bioactive L-OddC and 3TC, has been developed via TMSCl/pyridine induced stereoselective Reformatskii-Claisen rearragement of secondary allyl chlorodifluoroacetate and then a regioselective Pummerer reaction to introduce bases.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000264023500017
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/17659
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Zheng F,Zhang XG,Qing FL. Stereoselective Reformatskii-Claisen rearrangement: synthesis of 2 ',3 '-dideoxy-6 ',6 '-difluoro-2 '-thionucleosides[J]. Chem. Commun.,2009(12):1505-1507.
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