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学科主题: 氟化学
题名: 二氟亚甲基取代的Goniodiol类似物的合成
其他题名: Synthesis of gem-difluoromethylenated goniodiol
作者: 谢阳芬 ; 徐修华 ; 乐旭义 ; 游正伟 ; 卿凤翎
通讯作者: 卿凤翎
刊名: 有机化学
发表日期: 2008-01-01
卷: 28, 期:2, 页:283-287
收录类别: SCI
部门归属: 东华大学; 有机所
英文摘要: An efficient and general route to gem-difluoromethylenated goniodiol has been developed. The introduction of a gem-difluoromethylene group was achieved by indium-mediated difluoropropargylation of aldehyde. The alpha,beta-unsaturated-delta-lactone was successfully formed by the oxidation of 1,5-diols in the presence of catalytic 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO) and excess trichloroisocyanuric acid (TCCA).
语种: 中文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/17643
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
谢阳芬,徐修华,乐旭义,等. 二氟亚甲基取代的Goniodiol类似物的合成[J]. 有机化学,2008,28(2):283-287.
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