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学科主题: 氟化学 ; 金属有机化学
题名: Understanding the mechanism of Pd-catalyzed allylic substitution of the cyclic difluorinated carbonates
其他题名: Understanding the mechanism of Pd-catalyzed allylic substitution of the cyclic difluorinated carbonates
作者: Xu J(徐军) ; Qiu XL(邱小龙) ; Qing FL(卿凤翎)
通讯作者: 卿凤翎
刊名: Beilstein J. Org. Chem.
发表日期: 2008
卷: 4, 期:18, 页:1-5
收录类别: SCI
部门归属: 上海有机所; 东华大学
英文摘要: We present a mechanistic investigation of Pd-catalyzed allylic substitution of cyclic gem-difluorinated carbonates 1 and 4, previously employed in the synthesis of 3',3'-difluoro-2'-hydroxymethyl-4',5'-unsaturated carbocyclic nucleosides in 17 steps. The substitution features a reversal of regioselectivity caused by fluorine.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000256827300001
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/17639
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Xu J,Qiu XL,Qing FL. Understanding the mechanism of Pd-catalyzed allylic substitution of the cyclic difluorinated carbonates[J]. Beilstein J. Org. Chem.,2008,4(18):1-5.
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