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Synthesis and utilization of trifluoromethylated amino alcohol ligands for the enantio selective Reformatsky reaction and addition of diethylzinc to N-(diphenylphosphinoyl)imine
其他题名Synthesis and utilization of trifluoromethylated amino alcohol ligands for the enantio selective Reformatsky reaction and addition of diethylzinc to N-(diphenylphosphinoyl)imine
Xu XH(徐修华); Qiu XL(邱小龙); Qing FL(卿凤翎)
2008
发表期刊Tetrahedron
ISSN0040-4020
卷号64期号:30-31页码:7353-7361
摘要A series of trifluoromethylated amino alcohol ligands, which had been designed and conveniently prepared, were successfully applied in the enantioselective Reformatsky reaction and addition of diethylzinc to N-(diphenylphosphinoyl)imine,respectively. The influence of the substituents on C-3 position and the amino moiety on the enantioselectivity has been carefully investigated. in the best cases, ligand lb exhibited good selectivity for the enantioseiective Reformatsky reaction in 86% ee and ligand 12d provided excellent enantioselectivity in the addition of cliethylzinc to N-(diphenylphospbinoyl)imine with 95% ee. (c) 2008 Elsevier Ltd. All rights reserved.
学科领域氟化学 ; 生命有机化学
部门归属上海有机所; 东华大学
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收录类别SCI
语种英语
WOS记录号WOS:000257619700039
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文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/17633
专题中科院有机氟化学重点实验室
通讯作者Qing FL(卿凤翎)
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GB/T 7714
Xu XH,Qiu XL,Qing FL. Synthesis and utilization of trifluoromethylated amino alcohol ligands for the enantio selective Reformatsky reaction and addition of diethylzinc to N-(diphenylphosphinoyl)imine[J]. Tetrahedron,2008,64(30-31):7353-7361.
APA 徐修华,邱小龙,&卿凤翎.(2008).Synthesis and utilization of trifluoromethylated amino alcohol ligands for the enantio selective Reformatsky reaction and addition of diethylzinc to N-(diphenylphosphinoyl)imine.Tetrahedron,64(30-31),7353-7361.
MLA 徐修华,et al."Synthesis and utilization of trifluoromethylated amino alcohol ligands for the enantio selective Reformatsky reaction and addition of diethylzinc to N-(diphenylphosphinoyl)imine".Tetrahedron 64.30-31(2008):7353-7361.
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