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学科主题: 氟化学 ; 生命有机化学
题名: Synthesis of 3-deoxy-3,3-difluoro-D-ribohexose from gem-difluorohomoallyl alcohol
其他题名: Synthesis of 3-deoxy-3,3-difluoro-D-ribohexose from gem-difluorohomoallyl alcohol
作者: Xu XH(徐修华) ; You ZW(游正伟) ; Zhang XG(张新刚) ; Qing FL(卿凤翎)
通讯作者: 卿凤翎
刊名: J. Fluor. Chem.
发表日期: 2007
卷: 128, 期:5, 页:535-539
收录类别: SCI
部门归属: 上海有机所; 东华大学
英文摘要: A novel synthetic route to 3-deoxy-3,3-difluoro-D-ribohexose I has been developed. Dihydroxidation of gem-difluorohomoallyl alcohol followed by several steps of protection and deprotection gave key intermediate 9. Oxidation of 1,5-diol 9 with 2 equiv. trichloroisocyanuric acid and catalytic TEMPO gave lactone 10. Reduction of 10 with DIBAL-H followed by deprotections afforded the target molecule 1. (C) 2007 Elsevier B.V. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000246429100009
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/17603
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Xu XH,You ZW,Zhang XG,et al. Synthesis of 3-deoxy-3,3-difluoro-D-ribohexose from gem-difluorohomoallyl alcohol[J]. J. Fluor. Chem.,2007,128(5):535-539.
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