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学科主题: 氟化学
题名: Reductive radical reaction of gem-difluorinated organoselenium compounds with an indium(III) chloride-sodium borohydride system bromodifluoromethyl phenyl selenide
其他题名: 应用InCl3/NaBH4对含二氟亚甲基的有机硒化合物进行自由基还原反应
作者: Qin YY(秦盈盈) ; Yang YY(杨严严) ; Qiu XL(邱小龙) ; Qing FL(卿凤翎)
通讯作者: 卿凤翎
刊名: Synthesis
发表日期: 2006-01-01
期: 9, 页:1475-1479
收录类别: SCI
部门归属: 东华大学; 中科院上海有机化学研究所
英文摘要: As for gem-difluorinated phenylseleno compounds, indium hydride, in situ generated by transmetallation between InCl3 and NaBH,, was found to be a convenient radical reagent as an alternative to tributyltin hydride. Besides its excellent performance in intramolecular cyclization and radical deselenylation, the NaBH4/InCl3 system also succeeded in intermolecular radical addition between organoselenium compounds and styrene.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/17581
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Qin YY,Yang YY,Qiu XL,et al. Reductive radical reaction of gem-difluorinated organoselenium compounds with an indium(III) chloride-sodium borohydride system bromodifluoromethyl phenyl selenide[J]. Synthesis,2006(9):1475-1479.
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