中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 中科院有机氟化学重点实验室  > 期刊论文
学科主题: 氟化学
题名: Stereocontrolled synthesis of gem-difluoromethylenated goniodiols and goniothalamin epoxides based on ring-closing metathesis metathesis; alpha,beta-unsaturated-delta-tactone
其他题名: 基于RCM反应合成含二氟亚甲基的Goniodiols和Goniothalamin过氧化物
作者: You ZW(游正伟) ; Zhang XG(张新刚) ; Qing FL(卿凤翎)
刊名: Synthesis
发表日期: 2006-01-01
期: 15, 页:2535-2542
收录类别: SCI
部门归属: 中科院上海有机化学研究所; 东华大学
英文摘要: An efficient and general method to stereoselectively synthesize gem-difluoromethylenated goniodiols and goniothalamin epoxides has been developed. The introduction of a gem-difluoromethyl-containing group was achieved by the reaction of aldehydes with 3-bromo-3,3-difluoropropene in the presence of indium. The gem-difluoromethylenated alpha,beta-unsaturated-8-lactone moiety was constructed through the ring-closing metathesis of highly electron-deficient gem-difluoromethylenated acryloyl esters by Grubbs' II catalyst in toluene at reflux.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/17575
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2006089.pdf(46KB)----开放获取--View Download

Recommended Citation:
You ZW,Zhang XG,Qing FL. Stereocontrolled synthesis of gem-difluoromethylenated goniodiols and goniothalamin epoxides based on ring-closing metathesis metathesis; alpha,beta-unsaturated-delta-tactone[J]. Synthesis,2006(15):2535-2542.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[游正伟]'s Articles
[张新刚]'s Articles
[卿凤翎]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[游正伟]‘s Articles
[张新刚]‘s Articles
[卿凤翎]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2006089.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace