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学科主题: 氟化学
题名: Synthesis and transformation of [difluoro(phenylseleno)methyl]trimethylsilane
其他题名: PhSeCF2TMS的合成与转化
作者: Qin YY(秦盈盈) ; Qiu XL(邱小龙) ; Yang YY(杨严严) ; Qing FL(卿凤翎)
通讯作者: 卿凤翎
刊名: J. Org. Chem.
发表日期: 2005
卷: 70, 期:22, 页:9040-9043
收录类别: SCI
部门归属: 东华大学; 上海有机所元素有机
英文摘要: A novel and efficient strategy was developed to synthesize [difluoro(phenylseleno)methyl]trimethylsilane (PhSeCF2-TMS, 2), which was further utilized as a nucleophilic difluoromethylating reagent to incorporate the difluoro(phenylseleno)methyl (PhSeCF2) group into carbonyl compounds in good yields. The resulting PhSeCF2-containing alcohols 3 could be conveniently converted into corresponding difluoromethyl alcohols 4 by a radical deselenylation.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000232909300056
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/17557
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Qin YY,Qiu XL,Yang YY,et al. Synthesis and transformation of [difluoro(phenylseleno)methyl]trimethylsilane[J]. J. Org. Chem.,2005,70(22):9040-9043.
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