中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 中科院有机氟化学重点实验室  > 期刊论文
学科主题: 氟化学
题名: Preparation, properties and synthetic potentials of fluorous boronates
其他题名: 氟碳相硼酸酯的制备、性能及合成应用
作者: Huang YG(黄焰根) ; Chen DJ(陈大军) ; Qing FL(卿凤翎)
通讯作者: 卿凤翎
刊名: Tetrahedron
发表日期: 2003
卷: 59, 期:40, 页:7879-7886
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所元素有机化学实验室
英文摘要: A fluorous approach to the chemistry of boronic acids and its application in fluorous-phase techniques are described. Treatment of fluomus bromosilane 2 with allyl Grignard reagent followed by dihydroxylation provided fluorous diol 1. A series of boronic acids were attached to 1 by esterification. The formed fluorous boronates 4 were moisture sensitive and thus their synthetic potentials were limited. Thus a fluorous pinacol, 5, was designed and synthesized by treatment of fluorous bromosilane 2 with excess 2,3-dimethyl-2-butyenylmagnesium bromide 9 to afford fluorous tetramethyl ethene 8, and was dihydroxylated. Compound 5 was successfully used to prepare fluorous boronates in a one-pot process from organic bromides. We have demonstrated that olefin cross-metathesis can be caoied out in a fluorous version. It is noteworhy that all of the auorinated componnds reponed in this paper were purified by simple liquid extraction.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000185585800004
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/17499
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2003085.pdf(241KB)----开放获取--View Download

Recommended Citation:
Huang YG,Chen DJ,Qing FL. Preparation, properties and synthetic potentials of fluorous boronates[J]. Tetrahedron,2003,59(40):7879-7886.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[黄焰根]'s Articles
[陈大军]'s Articles
[卿凤翎]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[黄焰根]‘s Articles
[陈大军]‘s Articles
[卿凤翎]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2003085.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace