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学科主题: 氟化学 ; 金属有机化学
题名: Synthesis of 3-trifluoroethylfurans by palladium-catalyzed cyclization-Isomerization of (Z)-2-alkynyl-3-trifluoromethyl allylic alcohols
其他题名: 通过钯催化(Z)-2-烷炔基-3三氟甲基烯丙醇的环化异构化反应合成3-三氟乙基呋喃
作者: Qing FL(卿凤翎) ; Gao WZ(高文忠) ; Ying JW(应洁文)
通讯作者: 卿凤翎
刊名: J. Org. Chem.
发表日期: 2000
卷: 65, 期:7, 页:2003-2006
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所氟有机化学开放实验室
英文摘要: Hydroiodonation of trifluoromethyl propargylic alcohols 1 regio-and stereoselectively produce (Z)-2-iodo-3-trifluoromethyl allylic alcohols 2. (Z)-2-alkynyl-3-trifluoromethyl allylic alcohols 5, available throuph PD(PPh^3)^4-mediated coupling of 2 and terminal alkynes 4, cyclize and subsequently isomerize to 3-trifluoroethylfurans 6 upon catalysis under PdCl^2(CH^#CN)^2 in THF at 5-10℃
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000086348400013
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/17471
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Qing FL,Gao WZ,Ying JW. Synthesis of 3-trifluoroethylfurans by palladium-catalyzed cyclization-Isomerization of (Z)-2-alkynyl-3-trifluoromethyl allylic alcohols[J]. J. Org. Chem.,2000,65(7):2003-2006.
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