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学科主题: 氟化学
题名: Fluorine-containing optically active allylic alcohols: preparation and claisen rearrangement as a new entry to highly functionalized fluorinated amino alcohol derivatives.
其他题名: 含氟光学活性烯丙醇: 制备和克莱森重排生成高官能团化的含氟氨基酸衍生物
作者: Peng S(彭晟) ; Qing FL(卿凤翎)
通讯作者: 卿凤翎
刊名: J. Chem. Soc.-Perkin Trans. 1
发表日期: 1999-01-01
页: 3345-3348
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所有机氟化学开放实验室
英文摘要: The reaction of Garner aldehyde 1 with 2-bromo-3,3,3-trifluoropropene in the presence of Zn-Ag couple gave the fluorine-containing, optically active allylic alcohol 2 in 65% yield with a diastereomeric excess greater than 98%. The treatment of Garner aldehyde 1 with CF=3CFBr=2(3a) and CF=3CCl=3(3b) in the presence of zinc powder and caalytic AlCl=3 highly diastereoselectively afforded 4a and 4b, respectively, in moderate yield. The orthoester Claisen rearrangement of 4a, b and 2 provided a new way to highly functionalized amino alcohol derivatives 6a-f containing a limited number of fluorine atoms.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/17445
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Peng S,Qing FL. Fluorine-containing optically active allylic alcohols: preparation and claisen rearrangement as a new entry to highly functionalized fluorinated amino alcohol derivatives.[J]. J. Chem. Soc.-Perkin Trans. 1,1999:3345-3348.
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