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学科主题: 氟化学
题名: The reaction of organozinc reagents with triftuoroacylated phosphonates: Synthesis of trifluoromethytated alpha, beta-unsaturated esters with an active methylene moiety
其他题名: 有机锌化合物和三氟酰基膦酸的反应。合成具有活泼亚甲基的三氟甲基α,β-不饱和酸酯
作者: Shen YC(沈延昌) ; Ni JH(倪家宏)
通讯作者: 沈延昌
刊名: Heteroatom Chem.
发表日期: 2004
卷: 15, 期:4, 页:289-292
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学实验室
英文摘要: The consecutive reaction of phosphonates 1 with n-butyllithium, trifluoroacetic anhydride, and organozinc compounds gives trifluoromethylated alpha, beta-unsaturated esters with an active methylene moiety and predominant Z-selectivity in 54-78% (3 steps) yields. (C) 2004 Wiley Periodicals, Inc.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000221692900001
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/17013
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Shen YC,Ni JH. The reaction of organozinc reagents with triftuoroacylated phosphonates: Synthesis of trifluoromethytated alpha, beta-unsaturated esters with an active methylene moiety[J]. Heteroatom Chem.,2004,15(4):289-292.
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