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学科主题: 氟化学
题名: A novel route to polyfluorinated alka-2E,4E-dienes
其他题名: 一条新奇的道多氟2E,4E-双烯的途径
作者: Shen YC(沈延昌) ; Wang GP(王国平)
通讯作者: 沈延昌
刊名: Synthesis
发表日期: 2004
期: 7, 页:999-1002
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学实验室
英文摘要: Treatment of (Z)-alpha-Fluoro-beta-trifluoromethylvinylstananes 3 with n-butyllithium gave tetrafluoropropene anion 4, which was reacted with alpha.beta-unsaturated aldehydes affording 6. With or without isolation of 6. DAST was added and reacted with 6 to give polyfluorinated alka-2E,4E isomers, exclusively. It is noteworthy that the migration of the double bond occurred only at the non-fluorine-containing one.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000221429700006
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/17011
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Shen YC,Wang GP. A novel route to polyfluorinated alka-2E,4E-dienes[J]. Synthesis,2004(7):999-1002.
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