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学科主题: 金属有机化学
题名: Synthesis, reactivity and crystal structure of perfluoroalkylated diethoxyphosphinyl triphenylphosphorane
其他题名: 全金属烷基二乙氧膦酰基三苯基膦的合成、反应性和晶体结构
作者: Jiang GF(江国防) ; Sun J(孙杰) ; Shen YC(沈延昌)
通讯作者: 沈延昌
刊名: J. Fluor. Chem.
发表日期: 2001-01-01
卷: 108, 期:2, 页:207-210
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: Synthesis and reactivity of perfluoroalkylated diethoxyphosphinyl triphenylphosphoranes is described. The crystal structure of [(1-diethoxyphosphinyl)-(-dimethylmethylidene)-3,3,4,4,4-pentafluorobutylidene]triphenylphosphorane has been determined and the bond P-(ylide) order is 1.84 which accounts for its lower reactivity with benzaldehyde than diethoxyphosphinylmethylidene triphenylphosphorane.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000168879700010
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/16971
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Jiang GF,Sun J,Shen YC. Synthesis, reactivity and crystal structure of perfluoroalkylated diethoxyphosphinyl triphenylphosphorane[J]. J. Fluor. Chem.,2001,108(2):207-210.
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