中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 中科院有机氟化学重点实验室  > 期刊论文
学科主题: 氟化学
题名: One-pot steroselective synthesis of trifluoromethylated penta-(2Z,4E)-dienenitriles viadouble olefination
其他题名: “一锅法”立体选择性地合成三氟甲基(2Z, 4E)-戊二烯腈通过双烯化反应
作者: Shen YC(沈延昌) ; Ni JH(倪家宏) ; Li P(李平) ; Sun J(孙杰)
通讯作者: 沈延昌
刊名: J. Chem. Soc.-Perkin Trans. 1
发表日期: 1999-01-01
页: 509-512
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: A novel double olefination via sequential transformation of diethyl(1-cyanoethyl)phosphonate and its application to the synthesis of substituted trifluoromethylated pentadienenitriles with 2Z,4E-isomers formed exclusively in 71--85% yield are described. This reaction is of broad scope since R may be alkyl, aryl or a heterocyclic group. The configuration of the products was ascertained on the basis of X-ray crystallographic analysis. The stereochemical results are rationalized by the proposed mechanism.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/16945
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
990126.pdf(376KB)----开放获取--View Download

Recommended Citation:
Shen YC,Ni JH,Li P,et al. One-pot steroselective synthesis of trifluoromethylated penta-(2Z,4E)-dienenitriles viadouble olefination[J]. J. Chem. Soc.-Perkin Trans. 1,1999:509-512.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[沈延昌]'s Articles
[倪家宏]'s Articles
[李平]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[沈延昌]‘s Articles
[倪家宏]‘s Articles
[李平]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 990126.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace