中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 中科院天然产物有机化学重点实验室  > 期刊论文
学科主题: 金属有机化学
题名: Highly Enantioselective Arylation of N-Tosylalkylaldimines Catalyzed by Rhodium-Diene Complexes
其他题名: Highly Enantioselective Arylation of N-Tosylalkylaldimines Catalyzed by Rhodium-Diene Complexes
作者: Cui Z(崔哲) ; Yu HJ(于宏杰) ; Yang RF(杨瑞峰) ; Gao WY(高文运) ; Feng CG(冯陈国) ; Lin GQ(林国强)
通讯作者: 冯陈国 ; 林国强
刊名: J. Am. Chem. Soc.
发表日期: 2011-01-01
卷: 133, 期:32, 页:12394-12397
收录类别: SCI
部门归属: 中科院上海有机化学研究所; 西北大学
英文摘要: A highly enantioselective rhodium-catalyzed arylation of aliphatic N-tosylaldimines has been developed. The combination of chiral bicyclo[3.3.0]octadiene ligands, an active rhodium hydroxide complex, and neutral reaction conditions is the key to achieving high yield and enantioselectivity. The application of this method is demonstrated by the enantioselective synthesis of chiral 2-aryl pyrrolidines and piperidines in a one-pot procedure. Furthermore, excellent results are also obtained for the imine substrates with the more readily cleavable N-nosyl protecting group.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000294740000020
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/16721
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2011354.pdf(798KB)----开放获取--View Download

Recommended Citation:
Cui Z,Yu HJ,Yang RF,et al. Highly Enantioselective Arylation of N-Tosylalkylaldimines Catalyzed by Rhodium-Diene Complexes[J]. J. Am. Chem. Soc.,2011,133(32):12394-12397.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[崔哲]'s Articles
[于宏杰]'s Articles
[杨瑞峰]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[崔哲]‘s Articles
[于宏杰]‘s Articles
[杨瑞峰]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2011354.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace