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Highly Enantioselective Synthesis of (Diarylmethyl)amines by Rhodium-Catalyzed Arylation of N-Nosylimines Using a Chiral Bicyclo[3.3.0]diene Ligand
Alternative Title铑/双烯催化对硝基苯磺酰亚胺的高选择性不对称芳基化反应合成双芳基甲基胺
WANG LI; Wang ZQ(王智谦); Xu MH(徐明华); Lin GQ(林国强)
2010
Source PublicationSynthesis
ISSN0039-7881
Issue19Pages:3263-3267
AbstractA highly efficient asymmetric arylation of N-nosylimines with arylboronic acids catalyzed by a rhodium-diene complex is described. A wide range of enantiopure (98-99% ee) N(diarylmethyl)nosylamides, as well as (3S)-2-(4-nosyl)-3-phenyl-isoindolin-1-one, were obtained in high yields (83-99%) under very mild conditions.
Subject Area金属有机化学
Department中国科学院上海药物研究所; 中国科学院上海有机化学研究所
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Indexed BySCI
Language英语
WOS IDWOS:000282106600005
Citation statistics
Cited Times:20[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/16697
Collection中科院天然产物有机化学重点实验室
Corresponding AuthorXu MH(徐明华); Lin GQ(林国强)
Recommended Citation
GB/T 7714
WANG LI,Wang ZQ,Xu MH,et al. Highly Enantioselective Synthesis of (Diarylmethyl)amines by Rhodium-Catalyzed Arylation of N-Nosylimines Using a Chiral Bicyclo[3.3.0]diene Ligand[J]. Synthesis,2010(19):3263-3267.
APA WANG LI,王智谦,徐明华,&林国强.(2010).Highly Enantioselective Synthesis of (Diarylmethyl)amines by Rhodium-Catalyzed Arylation of N-Nosylimines Using a Chiral Bicyclo[3.3.0]diene Ligand.Synthesis(19),3263-3267.
MLA WANG LI,et al."Highly Enantioselective Synthesis of (Diarylmethyl)amines by Rhodium-Catalyzed Arylation of N-Nosylimines Using a Chiral Bicyclo[3.3.0]diene Ligand".Synthesis .19(2010):3263-3267.
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