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学科主题: 天然产物有机化学
题名: Assembly of a three-dimensional array of glycoconjugates by combinatorial biocatalysis in nonaqueous media
其他题名: Assembly of a three-dimensional array of glycoconjugates by combinatorial biocatalysis in nonaqueous media
作者: YU HUILEI ; Xu JH(许建和) ; WANG YUXIAO ; Lu WY(卢文芽) ; Lin GQ(林国强)
通讯作者: 许建和
刊名: J. Comb. Chem.
发表日期: 2008
卷: 10, 期:1, 页:79-87
收录类别: SCI
部门归属: 华东理工大学; 上海有机所
英文摘要: Glycoconjugates can be artificially synthesized by combinatorial biocatalysis. An example is given in this paper describing the construction of glycoconjugates array by using glycosidase and lipase in nonaqueous media. This array was started from glucose, with three aryl alcohols as the aglycone moiety of glycosides and five acids or esters as acyl donors for combinatorial acylation of glycosides, affording a three-dimensional array containing about 30 members with diverse structures. The array would be more abundant if more aglycones and acyl donors with other structures were filled in. Indeed, diverse classes of carbohydrates besides glucose can also be employed for generating diverse glycoconjugates due to their different roles in numerous physiological responses. The composition and distribution of the demonstration glycoconjugates array was detected and evaluated by HPLC-MS with electrospray ionization. And also, the distribution of the artificial array can be adjusted by changing the molar ratio of the auxiliary materials.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000252409800013
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/16685
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
YU HUILEI,Xu JH,WANG YUXIAO,et al. Assembly of a three-dimensional array of glycoconjugates by combinatorial biocatalysis in nonaqueous media[J]. J. Comb. Chem.,2008,10(1):79-87.
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