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学科主题: 分析化学
题名: Study on mass spectrometric behavior of samarium di-iodide in tetrahydrofuran solution
其他题名: Study on mass spectrometric behavior of samarium di-iodide in tetrahydrofuran solution
作者: Zhou J(周静) ; Feng CG(冯陈国) ; Xu MH(徐明华) ; Lin GQ(林国强) ; Guo YL(郭寅龙)
通讯作者: 郭寅龙
刊名: Int. J. Mass Spectrom.
发表日期: 2008
卷: 270, 期:1-2, 页:62-67
收录类别: SCI
部门归属: 上海有机所, 上海药物所
英文摘要: The mass spectrometric behavior of the SmI2 in tetrahydrofuran (THF) solution was studied by ESI-Q-MS/MS and ESI-TOF-MS. Results obtained show that the trivalent samarium ions were the dominating species observed, which could be explained by the electron donor nature of the Sm-II. The rich coordination chemistry around Sm-II and Sm-III centers were also discussed. Besides, the fast ligand exchange of the THF-solvated samarium complexes with hexamethylphosphoramide (HMPA) was monitored by on-line ESI-Q-MS, which demonstrated the strong coordination of HMPA to samarium. (c) 2007 Elsevier B.V. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000253115800009
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/16683
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
Zhou J,Feng CG,Xu MH,et al. Study on mass spectrometric behavior of samarium di-iodide in tetrahydrofuran solution[J]. Int. J. Mass Spectrom.,2008,270(1-2):62-67.
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