Easily accessible C-2-symmetric chiral bicyclo[3.3.0] dienes as ligands for rhodium-catalyzed asymmetric 1,4-addition
其他题名Easily accessible C-2-symmetric chiral bicyclo[3.3.0] dienes as ligands for rhodium-catalyzed asymmetric 1,4-addition
Feng CG(冯陈国); Wang ZQ(王智谦); Tian P(田平); Xu MH(徐明华); Lin GQ(林国强)
2008
发表期刊Chem.-Asian J.
ISSN1861-4728
卷号3期号:8-9页码:1511-1516
摘要The synthesis of a new type of C-2-symmetric chiral diene ligands with a nonbridged bicyclic [3.3.0] backbone was successfully introduced. Using highly efficient lipase-catalyzed transesterification and Suzuki-coupling strategies, a broad family of enantiopure 3,6-disubstituted bicyclo[3.3.0] dienes with different electronic and steric properties could be easily prepared. The application of these new diene ligands in the Rh-catalyzed asymmetric 1,4-addition of arylboronic acids to alpha,beta-unsaturated carbonyl compounds have been examined, and excellent enantioselectivities (up to 98% ee) as well as good yields are achieved under very mild reaction conditions at room temperature.
学科领域金属有机化学
部门归属上海有机所
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收录类别SCI
语种英语
WOS记录号WOS:000259119400036
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被引频次:47[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/16669
专题中科院天然产物有机化学重点实验室
通讯作者Xu MH(徐明华); Lin GQ(林国强)
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GB/T 7714
Feng CG,Wang ZQ,Tian P,et al. Easily accessible C-2-symmetric chiral bicyclo[3.3.0] dienes as ligands for rhodium-catalyzed asymmetric 1,4-addition[J]. Chem.-Asian J.,2008,3(8-9):1511-1516.
APA 冯陈国,王智谦,田平,徐明华,&林国强.(2008).Easily accessible C-2-symmetric chiral bicyclo[3.3.0] dienes as ligands for rhodium-catalyzed asymmetric 1,4-addition.Chem.-Asian J.,3(8-9),1511-1516.
MLA 冯陈国,et al."Easily accessible C-2-symmetric chiral bicyclo[3.3.0] dienes as ligands for rhodium-catalyzed asymmetric 1,4-addition".Chem.-Asian J. 3.8-9(2008):1511-1516.
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