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学科主题: 金属有机化学
题名: Easily accessible C-2-symmetric chiral bicyclo[3.3.0] dienes as ligands for rhodium-catalyzed asymmetric 1,4-addition
其他题名: Easily accessible C-2-symmetric chiral bicyclo[3.3.0] dienes as ligands for rhodium-catalyzed asymmetric 1,4-addition
作者: Feng CG(冯陈国) ; Wang ZQ(王智谦) ; Tian P(田平) ; Xu MH(徐明华) ; Lin GQ(林国强)
通讯作者: 徐明华 ; 林国强
刊名: Chem.-Asian J.
发表日期: 2008
卷: 3, 期:8-9, 页:1511-1516
收录类别: SCI
部门归属: 上海有机所
英文摘要: The synthesis of a new type of C-2-symmetric chiral diene ligands with a nonbridged bicyclic [3.3.0] backbone was successfully introduced. Using highly efficient lipase-catalyzed transesterification and Suzuki-coupling strategies, a broad family of enantiopure 3,6-disubstituted bicyclo[3.3.0] dienes with different electronic and steric properties could be easily prepared. The application of these new diene ligands in the Rh-catalyzed asymmetric 1,4-addition of arylboronic acids to alpha,beta-unsaturated carbonyl compounds have been examined, and excellent enantioselectivities (up to 98% ee) as well as good yields are achieved under very mild reaction conditions at room temperature.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000259119400036
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/16669
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
Feng CG,Wang ZQ,Tian P,et al. Easily accessible C-2-symmetric chiral bicyclo[3.3.0] dienes as ligands for rhodium-catalyzed asymmetric 1,4-addition[J]. Chem.-Asian J.,2008,3(8-9):1511-1516.
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