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学科主题: 金属有机化学
题名: Highly practical catalytic asymmetric 1,4-addition of arylboronic acids in water using new hydrophilic chiral bicyclo[3.3.0] diene ligands
其他题名: Highly practical catalytic asymmetric 1,4-addition of arylboronic acids in water using new hydrophilic chiral bicyclo[3.3.0] diene ligands
作者: Feng CG(冯陈国) ; Wang ZQ(王智谦) ; SHAO CHENG ; Xu MH(徐明华) ; Lin GQ(林国强)
通讯作者: 徐明华 ; 林国强
刊名: Org. Lett.
发表日期: 2008
卷: 10, 期:18, 页:4101-4104
收录类别: SCI
部门归属: 上海有机所; 上海药物所
英文摘要: The first Rh-diene-catalyzed aqueous asymmetric 1,4-addition of alpha,6-unsaturated carbonyl compounds with arylboronic acids has been realized. By using a hydrophilic bicyclo[3.3.0] diene ligand, the reactions can be performed successfully in neat water at room temperature to afford the corresponding products in good yields and with very high enantioselectivities for both cyclic and linear substrates.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000259197600043
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/16667
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
Feng CG,Wang ZQ,SHAO CHENG,et al. Highly practical catalytic asymmetric 1,4-addition of arylboronic acids in water using new hydrophilic chiral bicyclo[3.3.0] diene ligands[J]. Org. Lett.,2008,10(18):4101-4104.
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