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Highly practical catalytic asymmetric 1,4-addition of arylboronic acids in water using new hydrophilic chiral bicyclo[3.3.0] diene ligands
Alternative TitleHighly practical catalytic asymmetric 1,4-addition of arylboronic acids in water using new hydrophilic chiral bicyclo[3.3.0] diene ligands
Feng CG(冯陈国); Wang ZQ(王智谦); SHAO CHENG; Xu MH(徐明华); Lin GQ(林国强)
2008
Source PublicationOrg. Lett.
ISSN1523-7060
Volume10Issue:18Pages:4101-4104
AbstractThe first Rh-diene-catalyzed aqueous asymmetric 1,4-addition of alpha,6-unsaturated carbonyl compounds with arylboronic acids has been realized. By using a hydrophilic bicyclo[3.3.0] diene ligand, the reactions can be performed successfully in neat water at room temperature to afford the corresponding products in good yields and with very high enantioselectivities for both cyclic and linear substrates.
Subject Area金属有机化学
Department上海有机所; 上海药物所
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Indexed BySCI
Language英语
WOS IDWOS:000259197600043
Citation statistics
Cited Times:75[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/16667
Collection中科院天然产物有机化学重点实验室
Corresponding AuthorXu MH(徐明华); Lin GQ(林国强)
Recommended Citation
GB/T 7714
Feng CG,Wang ZQ,SHAO CHENG,et al. Highly practical catalytic asymmetric 1,4-addition of arylboronic acids in water using new hydrophilic chiral bicyclo[3.3.0] diene ligands[J]. Org. Lett.,2008,10(18):4101-4104.
APA 冯陈国,王智谦,SHAO CHENG,徐明华,&林国强.(2008).Highly practical catalytic asymmetric 1,4-addition of arylboronic acids in water using new hydrophilic chiral bicyclo[3.3.0] diene ligands.Org. Lett.,10(18),4101-4104.
MLA 冯陈国,et al."Highly practical catalytic asymmetric 1,4-addition of arylboronic acids in water using new hydrophilic chiral bicyclo[3.3.0] diene ligands".Org. Lett. 10.18(2008):4101-4104.
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