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学科主题: 有机化学
题名: Samarium diiodide-promoted electrophilic amination of ketone enolates: efficient synthesis of quaternary carbon-containing alpha-aminated ketones
其他题名: Samarium diiodide-promoted electrophilic amination of ketone enolates: efficient synthesis of quaternary carbon-containing alpha-aminated ketones
作者: Sun XW(孙兴文) ; WANG WEI ; Xu MH(徐明华) ; Lin GQ(林国强)
通讯作者: 徐明华 ; 林国强
刊名: Tetrahedron Lett.
发表日期: 2008
卷: 49, 期:40, 页:5807-5809
收录类别: SCI
部门归属: 上海有机所; 上海药物所
英文摘要: An efficient and practical electrophilic amination method that allows the preparation of useful quaternary carbon-containing alpha-aminoketones was developed. The reaction proceeds regiospecifically via a samarium enolate intermediate at room temperature in the presence of mild reducing agent SmI2. Unlike the most reported lithium enolate cases, this new amination method does not require the use of strong base such as BuLi or LDA. (C) 2008 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000259537800027
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/16665
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
Sun XW,WANG WEI,Xu MH,et al. Samarium diiodide-promoted electrophilic amination of ketone enolates: efficient synthesis of quaternary carbon-containing alpha-aminated ketones[J]. Tetrahedron Lett.,2008,49(40):5807-5809.
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