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学科主题: 生命有机化学
题名: Lipase-catalyzed desymmetrization of quaternary carbon-containing 1,3-propanediols: A new entry to the asymmetric synthesis of alpha-substituted serine analogues 2-nitropropane-1,3-diols
其他题名: 脂酶催化的季碳1,3-丙二醇去对称化反应:一种不对称合成2-取代丝氨酸类似物的新方法
作者: Tian P(田平) ; Xu MH(徐明华) ; Wang ZQ(王智谦) ; Li ZY(李祖义) ; Lin GQ(林国强)
通讯作者: 林国强
刊名: Synlett
发表日期: 2006-01-01
期: 8, 页:1201-1204
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所
英文摘要: A new approach to the asymmetric synthesis of alpha-substiluted serine analogues was developed. The method utilizes a lipase-catalyzed esterification desymmetrization protocol. In the presence of PPL, a series of benzyl-substituted quaternary 2-nitropropane-1,3-diols were successfully desymmetrized by selective acetylation in very good yields and enantioselectivities (up to 95% ee).
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/16653
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
Tian P,Xu MH,Wang ZQ,et al. Lipase-catalyzed desymmetrization of quaternary carbon-containing 1,3-propanediols: A new entry to the asymmetric synthesis of alpha-substituted serine analogues 2-nitropropane-1,3-diols[J]. Synlett,2006(8):1201-1204.
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