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学科主题: 有机化学
题名: (1S)-1-ethyl-2-methylpropyl 3,13-dimethylpentadecanoate: Major sex pheromone component of Paulownia bagworm, Clania variegata 1-ethyl-2-methylpropyl 3,13-dimethylpentadecanoate
其他题名: (1S)-1-乙基-2-甲丙基3,13-二甲基十五烷酸酯
作者: Gries R. ; Khaskin G. ; Tan ZX(谈忠兴) ; Zhao B. G. ; King G. G. S. ; Miroshnychenko, A. ; Lin GQ(林国强) ; Rhainds M. ; Gries G.
通讯作者: Gries G.
刊名: J. Chem. Ecol.
发表日期: 2006-01-01
卷: 32, 期:8, 页:1673-1685
收录类别: SCI
部门归属: Simon Fraser University; 中科院上海有机化学研究所
英文摘要: The Paulownia bagworm, Clania variegata Snell. (Lepidoptera: Psychidae), is one of the most significant forest defoliators in China. In gas chromatographic (GC)-electroantennographic detection analyses of pheromone gland extracts of female C. variegata on three GC columns (DB-5, DB-23, DB-210), two compounds (A and B) elicited strong responses from male antennae. The more abundant component B was isolated by high-performance liquid chromatography and identified as 1-ethyl-2-methylpropyl 3,13-dimethylpentadecanoate by transesterification, GC-mass spectrometry (MS), and comparison of its spectral and GC retention characteristics with those of synthetic compounds. In field trapping experiments in China, racemic and (1S)-1-ethyl-2-methylpropyl 3,13-dimethylpentadecanoate [but not the (1R)-stereoisomer] attracted male C. variegata. The absolute configuration of B (a molecule with three chiral centers) and the structure of component A remain to be determined.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/16651
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
Gries R.,Khaskin G.,Tan ZX,et al. (1S)-1-ethyl-2-methylpropyl 3,13-dimethylpentadecanoate: Major sex pheromone component of Paulownia bagworm, Clania variegata 1-ethyl-2-methylpropyl 3,13-dimethylpentadecanoate[J]. J. Chem. Ecol.,2006,32(8):1673-1685.
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