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学科主题: 有机化学
题名: Room-temperature highly diastereoselective Zn-mediated allylation of chiral N-tert-butanesulfinyl imines: Remarkable reaction condition controlled stereoselectivity reversal
其他题名: 室温下金属锌参与的高非对映选择性的N-叔丁基亚磺酰胺的烯丙基化反应:优异的控制选择性翻转的反应条件
作者: Sun XW(孙兴文) ; Xu MH(徐明华) ; Lin GQ(林国强)
通讯作者: 徐明华 ; 林国强
刊名: Org. Lett.
发表日期: 2006
卷: 8, 期:21, 页:4979-4982
收录类别: SCI
部门归属: 中国科学院上海有机化学研究; 中国科学院上海药物所
英文摘要: An efficient method for the highly diastereoselective synthesis of chiral homoallylic amines by Zn-mediated allylation of chiral N-tert-butanesulfinyl imines at room temperature was developed. By simply tuning the reaction conditions, the method allows the achievement of a highly remarkable opposite stereocontrol, affording the desired stereochemical outcome in good yield and with excellent diastereoselectivity (up to 98% dr). With N-sulfinyl ketimines, the corresponding quaternary carbon-containing chiral homoallylic amines could also be produced.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000241030900078
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/16649
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
Sun XW,Xu MH,Lin GQ. Room-temperature highly diastereoselective Zn-mediated allylation of chiral N-tert-butanesulfinyl imines: Remarkable reaction condition controlled stereoselectivity reversal[J]. Org. Lett.,2006,8(21):4979-4982.
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