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学科主题: 生命有机化学
题名: Asymmetric synthess aided by biocatalysts
其他题名: 生物催化剂催化的不对称合成
作者: Chen PR(陈沛然) ; Gu JX(顾建新) ; Wei ZL(魏志亮) ; Han SQ(韩世清) ; Li ZY(李祖义) ; Lin GQ(林国强)
通讯作者: 林国强
刊名: Chin. J. Chem.
发表日期: 2003-01-01
卷: 21, 期:8, 页:983-993
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所现代有机合成化学实验室
英文摘要: This article summarizes the achievements of the authors'group in the area of biocatalyst-catalyzed organic reactions in recent 10 years. A strain of Geotrichum sp. Obtained by screening is capable of stereoselectively reducing a number of carbonyl compounds. In many cases, the stereochemistryis complementary with that obtained jby baker's yeast. Therefore, this microorganism provides a useful pathway to the preparation of alcohol compounds with specific configurations. On the other hand, a number of plant sources have been screened for oxynitrilases and the hydrocyanation reactions of vaious arylcarboxaldetem" was invented, by which a series of novel optcally active cyanhydrins were prepared. On this basis, a high through-put continuous reaction system has been designed. This paper also describes examples of the syntheses of bio-asctive compounds by using jthe optically active compounds obtained from the abovementioned catalytic reactions as precursors.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/16613
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
Chen PR,Gu JX,Wei ZL,et al. Asymmetric synthess aided by biocatalysts[J]. Chin. J. Chem.,2003,21(8):983-993.
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